92758
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92758
Fluka
Trimethyl(methylthio)silane
purum, ≥97.0% (GC)
| Synonym: | (Methylthio)trimethylsilane, Methyl trimethylsilyl sulfide, Trimethylsilyl methyl sulfide |
| CAS Number: | 3908-55-2 |
| Linear Formula: | (CH3)3SiSCH3 |
| Molecular Weight: | 120.29 |
| Beilstein Registry Number: | 2035839 |
| EC Number: | 223-466-9 |
| MDL number: | MFCD00042843 |
| PubChem Substance ID: | 24889716 |
Description
| Other Notes | Reagent for the thioacetalisation of carbonyl compounds1; Review2; Silylating agent3 |
Properties
| grade | purum |
| assay | ≥97.0% (GC) |
| refractive index | n |
| n | |
| bp | 110-114 °C(lit.) |
| density | 0.848 g/mL at 25 °C(lit.) |
Safety
| Personal Protective Equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
| Hazard Codes | Xi |
| Risk Statements | 10-36/37/38 |
| Safety Statements | 26-36 |
| RIDADR | UN1993 3/PG 2 |
| WGK Germany | 3 |
| Flash Point(F) | 37.4 °F |
| Flash Point(C) | 3 °C |
References
| Cited Reference | 1. D.A. Evans et al. J. Am. Chem. Soc. 99, 5009, (1977) |
| 2. W.C. Groutas, D. Felker Synthesis, 861, (1980) | |
| 3. M. Fiorenza et al. J. Org. Chem. 49, 551, (1984) | |
| reference | FT-IR 2 (3), 4389:D / FT-NMR 1 (3), 675:B / RegBook 1 (2), 2977:G / Structure Index 1, 471:E:6 |
